Scientists have known for two decades about a more environmentally friendly way to cool large buildings that is less expensive than conventional cooling systems. The challenge has been making those systems efficient for everyday use.

New research at Pacific Northwest National Laboratory (PNNL) shows researchers are moving toward perfecting the technique.

The findings, published in the Journal of the American Chemical Society, show the important molecular understanding and interplay of pore-engineering and refrigerant required to create an improved metal-organic framework (MOF) for adsorption cooling.

The researchers, led by PNNL materials scientist Radha Kishan Motkuri, reported a dramatic increase—at least 40 per cent—in the efficiency of their pore-engineered MOFs.

These metal-ion clusters are porous compounds that take advantage of the adsorption and desorption—the attachment and release—of vapour on and from the surface of refrigerants.

Efficient MOF-cooling systems can now be integrated with conventional refrigeration and air conditioning systems because both use the same refrigerants and evaporator/condenser components.

The electric-powered compressor can be turned off when heat is available, like from a solar panel or geothermal resource, to run an MOF-based thermal compressor. Sorption-based cooling systems thus could ease the stress on electricity supplies.

The research builds upon PNNL’’s award winning MARCool technology.

That innovation created a new class of solid-state cooling technology that operates on wasted heat from power sources such as generators that could lead to significant energy and cost savings in homes, buildings, cars, trucks, navy ships, and industrial processes.

The International Energy Agency (IEA), the study notes, estimates that climate control units in buildings consume about 20 per cent of the world’s electricity. Global energy demand for space cooling is expected to triple that number by 2050.

Researchers at PNNL have made strides engineering MOFs as adsorbents that can adsorb, or "host," certain refrigerants.

Researchers tested how the common refrigerant, fluorocarbon R134a, performed at the atomic level with MOFs they manipulated to contain a high pore volume and density of open metal centres, Motkuri said.

“By increasing these saturation limits, we allow more fluorocarbon to be taken up by the sorbent per cycle of adsorption and desorption based on specified chiller process conditions,” he said.

For the last 10 years Motkuri has led material development for various fluorocarbon and water-based adsorption cooling systems.

“This increased throughput translates to a 400 per cent increase in the theoretical working capacity to cycle between adsorption/desorption state points,” he said.

“Ultimately, correlation of its bulk sorption performance under realistic chiller conditions results in modelled cooling capacities for the expanded MOF, Ni-TPM, that are at least 40 per cent larger than that of the parent MOF.”

Motkuri said researchers began to explore which material is the best to pair with the refrigerant to determine the most efficient MOF performance.

“We are engineering these materials to give a better performance,” he added.

Pete McGrail, a PNNL Laboratory Fellow, said the higher adsorbing capacity will result in a more efficient cooling system.

McGrail has led the laboratory’s adsorption cooling effort for several years. “This latest research exploits our new ability to custom design MOFs for improved performance in adsorption cooling systems,” he said.

The research was funded by DOE’s Geothermal Technologies Office (GTO). GTO also funded PNNL’s multilayered geothermal Harmonic Adsorption Recuperative Power (HARP) project, which includes materials development that requires a better understanding of the host-guest chemistry to find the best host material.

PNNL Research Team: Jian Zheng, Dushyant Barpaga, Manish Shetty, Papri Bhattacharya, Jeromy J. Jenks, B. Peter McGrail, and Radha Kishan Motkuri



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